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General Chemistry I

11 units, in the order of the UT Dallas course. Each starts from the experiment, and you run it. Open “What it covers” under a unit to see its topics and what is built.

By the end you can
  1. Use quantum theory and bonding theory to predict periodic trends, reactivity, and electronic and 3-D structures.
  2. Read experimental data, in tables and graphs, and solve problems by dimensional analysis with proper units and significant figures.
  3. Explain the role of energy in physical and chemical change, and do thermochemical calculations.
  4. Apply the gas laws and kinetic molecular theory to gases.

Exam 1

1
Atoms and the Periodic Table

What is matter really made of?

Describe the structure of the atom from the evidence for it, find protons, neutrons and electrons in any atom or ion, and work with isotopes and average atomic mass.

The moment The gold foil: an atom is almost all empty space, with a tiny, dense nucleus at the centre.

Ch 2Cathode ray tubeOil dropGold foilMass spectrometer
What it covers: 9 of 9 topics built
  • ✓ Dalton's atomic theory and the laws of conservation of mass, definite and multiple proportions (built)
  • ✓ The electron: charge-to-mass ratio (Thomson) (built)
  • ✓ The charge of the electron (Millikan) (built)
  • ✓ The nuclear atom (Rutherford) (built)
  • ✓ Radioactivity, the proton and the neutron (built)
  • ✓ Atomic number, mass number and isotopes (built)
  • ✓ Average atomic mass (built)
  • ✓ The periodic table: groups, periods, metals and nonmetals (built)
  • ✓ Molecules, ions and chemical formulas (empirical and molecular) (built)
2
Quantum Theory and Electronic Structure

Why does hydrogen glow in only a few colours?

Connect light to energy, read atomic spectra, use the Bohr model, and describe orbitals with quantum numbers.

The moment Standing waves: the energy levels fall straight out of the electron being a wave.

Ch 3BlackbodyPhotoelectric effectHydrogen spectrumElectron diffraction
What it covers: 10 of 10 topics built
  • ✓ Energy and its units (joules, electron-volts, kJ/mol) (built)
  • ✓ Waves: wavelength, frequency, c = λν; the electromagnetic spectrum (built)
  • ✓ Planck: energy comes in quanta, E = hν (built)
  • ✓ The photoelectric effect and photons (built)
  • ✓ The hydrogen emission spectrum and the Rydberg equation (built)
  • ✓ The Bohr model: energy levels, E = −13.6 eV / n² (built)
  • ✓ Matter waves: de Broglie wavelength, and why the levels exist (standing waves) (built)
  • ✓ The Heisenberg uncertainty principle (built)
  • ✓ Quantum numbers (n, l, mₗ, mₛ) and the shapes of orbitals (built)
  • ✓ Many-electron atoms: shells together, shielding and effective nuclear charge (built)
3
Periodic Trends of the Elements

Why does the periodic table have exactly this shape?

Write electron configurations and orbital diagrams, and predict how size, ionization energy, electron affinity and electronegativity change across the table, and why.

The moment The table builds itself, electron by electron, and the blocks come out 2, 6, 10 and 14 wide.

Ch 4Peeling an atomStern–GerlachIonization energies
What it covers: 7 of 7 topics built
  • ✓ Electron configurations: aufbau, Pauli, Hund; orbital diagrams (built)
  • ✓ Configurations and the periodic table (s, p, d, f blocks); valence electrons (built)
  • ✓ Paramagnetism and diamagnetism (built)
  • ✓ Atomic radius and its trend (built)
  • ✓ Ionization energy, including successive ionization energies (built)
  • ✓ Electron affinity and electronegativity (built)
  • ✓ Ions: electron configurations and ionic radii (built)

Exam 2

4
Ionic and Covalent Compounds

Why does table salt exist, and why is it a crystal?

Name compounds, write formulas, and tell ionic from covalent by their properties.

The moment Energy accounting: the energy released when ions pack into a lattice outweighs the cost of making them.

Ch 5Conductivity of solutionsMelting pointsLattice energy
What it covers: 5 of 5 topics built
  • ✓ Ionic and covalent bonding: how to tell them apart (built)
  • ✓ Ionic compounds: formulas and naming; polyatomic ions (built)
  • ✓ Lattice energy and the properties of ionic compounds (built)
  • ✓ Covalent (molecular) compounds: naming (built)
  • ✓ Acids: naming (built)
5
Representing Molecules

How do atoms share electrons, and what does a bond look like on paper?

Draw Lewis structures, assign formal charges, and judge resonance, bond order and bond energy.

The moment Resonance: ozone and benzene are none of the drawings you can make, and all of them at once.

Ch 6Bond lengthsBond energies
What it covers: 6 of 6 topics built
  • ✓ Lewis structures and the octet rule (built)
  • ✓ Exceptions to the octet rule (built)
  • ✓ Formal charge (built)
  • ✓ Resonance (built)
  • ✓ Bond order, bond length and bond energy (built)
  • ✓ Electronegativity and bond polarity (built)

Exam 3

6
Molecular Geometry, Intermolecular Forces and Bonding Theories

Why is water bent, and why does that make life possible?

Predict shape and polarity, relate intermolecular forces to properties, and use hybridization and molecular orbital theory.

The moment Electron clouds push apart into a shape; the shape makes water polar; polarity makes ice float.

Ch 7 and 12.2Water stream in an electric fieldBoiling pointsLiquid oxygen in a magnet
What it covers: 6 of 6 topics built
  • ✓ VSEPR theory and molecular geometry (built)
  • ✓ Molecular polarity and dipole moments (built)
  • ✓ Valence bond theory and hybridization; sigma and pi bonds (built)
  • ✓ Molecular orbital theory (built)
  • ✓ Intermolecular forces: dispersion, dipole-dipole, hydrogen bonding (built)
  • ✓ How intermolecular forces set boiling points and other properties (built)
7
Chemical Reactions

How do you count atoms you cannot see?

Balance equations and use the mole to run stoichiometry, limiting reagents and yield.

The moment The mole: weighing becomes counting, and a balanced equation turns into a recipe you can run backwards.

Ch 8Conservation of massCombustion analysisLimiting reagent
What it covers: 6 of 6 topics built
  • ✓ Chemical equations and balancing (built)
  • ✓ The mole, molar mass and Avogadro's number (built)
  • ✓ Stoichiometry: mass-mole-mass calculations (built)
  • ✓ Limiting reagent (built)
  • ✓ Theoretical, actual and percent yield (built)
  • ✓ Empirical formulas and combustion analysis (built)

Exam 4

8
Chemical Reactions in Aqueous Solutions

What really happens when salts dissolve and solutions mix?

Predict precipitates, balance acid-base and redox reactions, and do solution stoichiometry and titrations.

The moment Spectator ions: most of what is in the beaker is not reacting at all.

Ch 9Freezing-point depressionPrecipitationTitrationRedox
What it covers: 6 of 6 topics built
  • ✓ Solutions, molarity and dilution (built)
  • ✓ Electrolytes and the solubility rules (built)
  • ✓ Precipitation reactions and net ionic equations (built)
  • ✓ Acids and bases; neutralization (built)
  • ✓ Titration (built)
  • ✓ Oxidation-reduction reactions and oxidation numbers (built)
9
Energy Changes in Chemical Reactions

Where does the heat of a reaction come from?

Do thermochemical calculations: heat, enthalpy, calorimetry and Hess's law.

The moment Hess's law: energy adds up like arithmetic, whatever route the reaction takes.

Ch 10Joule's paddle wheelCoffee-cup calorimeterHess's law
What it covers: 5 of 5 topics built
  • ✓ Energy, heat and work; the first law of thermodynamics (built)
  • ✓ Enthalpy and enthalpy of reaction (built)
  • ✓ Calorimetry and specific heat (built)
  • ✓ Hess's law (built)
  • ✓ Standard enthalpies of formation (built)

Cumulative final

10
Gases

What is pressure, and why do all gases behave alike?

Use the gas laws and the kinetic molecular theory.

The moment The gas law is derived, not assumed, from nothing but colliding particles.

Ch 11Torricelli barometerBoyle's lawCharles's lawMolecular speeds
What it covers: 7 of 7 topics built
  • ✓ Pressure and its units (built)
  • ✓ The gas laws: Boyle, Charles, Gay-Lussac, Avogadro (built)
  • ✓ The ideal gas equation; molar volume and gas density (built)
  • ✓ Gas stoichiometry (built)
  • ✓ Dalton's law of partial pressures (built)
  • ✓ Kinetic molecular theory; molecular speeds; effusion and diffusion (built)
  • ✓ Real gases and the van der Waals equation (built)
11
Liquids and Solids

Why does ice melt at 0 degrees and a diamond not at 3,000?

Read phase diagrams and relate structure to the properties of liquids and solids.

The moment The phase diagram: every force from the earlier units draws one map of when matter is solid, liquid or gas.

Ch 12Vapor pressureHeating curveCrystal structuresPhase diagram
What it covers: 4 of 4 topics built
  • ✓ Liquids: vapor pressure, surface tension, viscosity (built)
  • ✓ Solids: crystalline and amorphous; unit cells and crystal types (built)
  • ✓ Phase changes and heating curves (built)
  • ✓ Phase diagrams (built)

Order and groupings follow the UT Dallas CHEM 1311 (Fall 2024 syllabus), which follows Chemistry: Atoms First, 5th edition (Burdge and Overby). An independent study resource, not affiliated with UT Dallas.